Metallation-induced migration of phosphorus from nitrogen to carbon in 1-oxo-2,8-diphenyl-2,5,8-triaza-1 lambda(5)-phosphabicyclo[3.3.0]octane: unusual bonding parameters of the double migration product

Authors
Bourne, SA He, ZJ Modro, TA Van Rooyen, PH
Citation
Sa. Bourne et al., Metallation-induced migration of phosphorus from nitrogen to carbon in 1-oxo-2,8-diphenyl-2,5,8-triaza-1 lambda(5)-phosphabicyclo[3.3.0]octane: unusual bonding parameters of the double migration product, CHEM COMMUN, (9), 1999, pp. 853-854
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
9
Year of publication
1999
Pages
853 - 854
Database
ISI
SICI code
1359-7345(19990507):9<853:MMOPFN>2.0.ZU;2-K
Abstract
The title compound undergoes lithiation-induced rearrangement, first to a b icyclic phosphonic diamide, and next to a bicyclic phosphinic amide; for th e latter product an unusually long phosphoryl bond was observed.