On the calculation and modeling of magnetic exchange interactions in weakly bonded systems: The case of the ferromagnetic copper(II) mu(2)-azido bridged complexes

The magnetic exchange interactions in copper(II) mu(2)-azido bridged comple xes have been studied using several density functionals and both GTO and ST O basis sets. From a methodological point of view, we have taken into prope r account nonorthogonality effects in the framework of the broken symmetry approach. A remarkable agreement with experimental data has been obtained u sing the crystallographic geometry and the new MPW1PW functional. However, modeling of the true ligands by ammonia molecules and complete optimization of the geometry of the isolated complex significantly deteriorate the resu lts. While this can lead to limitations on quantitative studies, general tr ends and magnetostructural correlations remain very significant. These resu lts are, furthermore, not very sensitive to technical details, like the for m of the functional or the type of basis set used.