VELOCITY OF SOUND AT 4 MHZ IN MERCURY NEAR ITS LIQUID-VAPOR CRITICAL-POINT

Citation
Bs. Dladla et al., VELOCITY OF SOUND AT 4 MHZ IN MERCURY NEAR ITS LIQUID-VAPOR CRITICAL-POINT, Zeitschrift für physikalische Chemie, 199, 1997, pp. 295-301
Citations number
13
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09429352
Volume
199
Year of publication
1997
Part
2
Pages
295 - 301
Database
ISI
SICI code
0942-9352(1997)199:<295:VOSA4M>2.0.ZU;2-O
Abstract
The sound velocity of mercury near its liquid-vapour critical point ha s been measured at 4 MHz with a pulse transmission-echo method. Accura te data could be obtained along several isotherms just below and above the critical temperature. The resulting velocity data along the criti cal isochore above T-c and in the liquid along the vapour-pressure cur ve show a finite velocity minimum at the critical point. The existence of such a minimum is consistent with the view that the critical behav iour of the metal mercury does not differ from that typical for molecu lar fluids.