Attempts to prepare NdFe9Si2 by are-melting and annealing produce alpha-Fe(
Si), Nd-2(Fe, Si)(17) and NdFe2Si2. As an alternative, we have produced amo
rphous samples by melt spinning. Amorphous NdFe9Si2 has a Curie temperature
of 405(5)K and an average Fe-57 hyperfine field of 18.2(3) T, at 295 K. Th
e amorphous phase undergoes two-stage crystallization with peak temperature
s of 897 and 924 K, ultimately producing Nd-2(Fe, Si)(17) and BCC alpha-Fe(
Si)A(2). (C) 1999 Published by Elsevier Science B.V. All rights reserved.