Methylcyclopentadienyl-vanadium(III) complexes

Authors
Bottcher, C Schmidt, H Rehder, D
Citation
C. Bottcher et al., Methylcyclopentadienyl-vanadium(III) complexes, J ORGMET CH, 580(1), 1999, pp. 72-76
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
580
Issue
1
Year of publication
1999
Pages
72 - 76
Database
ISI
SICI code
0022-328X(19990515)580:1<72:MC>2.0.ZU;2-5
Abstract
[(MeCp)VCl2(PEt3)(2)] (1) and [(MeCp)(2)VCl] (4) (MeCp = eta(5)-C5H4CH3)hav e been obtained from the reaction between VCl3 and NaMeCp in THF in the pre sence (1) and absence (4), respectively, of PEt3. The reaction of VCl3 and NaMeCp in the presence of CNt-Bu yielded (impure) [(MeCp)VCl2(CNt-Bu)(2)] ( 3) and, as a by-product, [(MeCp)(2)V(CNt-Bu)(2)][VCl4(THF)(2)] (2). The cry stal and molecular structures of 1, 2 and 4 have been determined. (C) 1999 Elsevier Science S.A. All rights reserved.