M. Galan-fereres et al., Synthesis and olefin polymerization using supported and non-supported geometry constrained titanium complexes, J ORGMET CH, 580(1), 1999, pp. 145-155
The synthesis of a constrained geometry titanium complex and its immobiliza
tion on different supports have been studied for the catalytic polymerizati
on of ethylene, propylene and styrene. The formation of higher molecular we
ight polymers was found in the heterogeneous system as compared to the homo
genous parent for polyethylene and polypropylene. Polymerization of propyle
ne yielded atactic products with elastomeric properties due to long polymer
chains. However, syndiotactic polymers were formed in the polymerization o
f styrene. Catalytic activity was found to be dependent on MAO and titanium
concentration; the higher the metal concentration the lower the activity o
f the catalyst. The activity of the heterogeneous system was determined as
a function of time, and a first-order deactivation pathway was found at roo
m temperature. The type of solvent (toluene or CH2Cl2) also played an impor
tant role in the polymerization of ethylene and styrene, although different
tendencies were found for either monomers. (C) 1999 Elsevier Science S.A.
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