CO2 laser photosensitised decomposition of 1,3-diphenyldisiloxane in the liquid phase: formation of poly(phenylsiloxanes) via extrusion insertion of phenylsilanone

Authors
Pola, J Plzak, Z Ouchi, A Kupcik, J Koga, Y
Citation
J. Pola et al., CO2 laser photosensitised decomposition of 1,3-diphenyldisiloxane in the liquid phase: formation of poly(phenylsiloxanes) via extrusion insertion of phenylsilanone, J ORGMET CH, 580(1), 1999, pp. 188-190
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
580
Issue
1
Year of publication
1999
Pages
188 - 190
Database
ISI
SICI code
0022-328X(19990515)580:1<188:CLPDO1>2.0.ZU;2-N
Abstract
CO2 laser-induced graphite-photosensitised decomposition of liquid 1,3-diph enyldisiloxane H2PhSiOSiPhH2 (DPDS) affords a blend of poly(phenylsiloxanes ) which are explained as formed via extrusion of PhHSi=O and its subsequent insertion into DPDS. (C) 1999 Elsevier Science S.A. All rights reserved.