Evaluation of the proton transfer kinetics of potential electrolytes in non-aqueous solutions using electrochemical techniques Part 1. Kinetic analysis of the general CE mechanism at stationary and rotating electrodes

Authors
Rebouillat, S Lyons, MEG Bannon, T
Citation
S. Rebouillat et al., Evaluation of the proton transfer kinetics of potential electrolytes in non-aqueous solutions using electrochemical techniques Part 1. Kinetic analysis of the general CE mechanism at stationary and rotating electrodes, J SOL ST EL, 3(4), 1999, pp. 215-230
Citations number
35
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
ISSN journal
14328488 → ACNP
Volume
3
Issue
4
Year of publication
1999
Pages
215 - 230
Database
ISI
SICI code
1432-8488(199905)3:4<215:EOTPTK>2.0.ZU;2-I
Abstract
The transport and kinetics of potential electrolytes (such as weak organic acids) at stationary and rotating electrodes have been examined in detail. A coherent mathematical analysis enabling the normalised current response t o be evaluated has been developed, and various rate limiting scenarios have been identified and examined.