H. Mori et al., Direct observation of MgCl2-supported Ziegler catalysts by high resolutiontransmission electron microscopy, MACRO RAPID, 20(5), 1999, pp. 245-250
The surface atomic structure of MgCl2 crystalline particles and MgCl2-suppo
rted Ziegler catalysts was observed by means of high resolution transmissio
n electron microscopy. Step-terrace surface structures, characteristic of t
he structure of the MgCl2 crystal, are found in the observed images of MgCl
2 particles. The observation of the structure of MgCl2-supported Ziegler ca
talysts shows that the MgCl2 crystals are severely deformed by the processe
s of catalyst preparation. Due to the preparation procedure used the struct
ure of the catalyst changes from crystalline to amorphous.