Direct observation of MgCl2-supported Ziegler catalysts by high resolutiontransmission electron microscopy

Citation
H. Mori et al., Direct observation of MgCl2-supported Ziegler catalysts by high resolutiontransmission electron microscopy, MACRO RAPID, 20(5), 1999, pp. 245-250
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
20
Issue
5
Year of publication
1999
Pages
245 - 250
Database
ISI
SICI code
1022-1336(199905)20:5<245:DOOMZC>2.0.ZU;2-D
Abstract
The surface atomic structure of MgCl2 crystalline particles and MgCl2-suppo rted Ziegler catalysts was observed by means of high resolution transmissio n electron microscopy. Step-terrace surface structures, characteristic of t he structure of the MgCl2 crystal, are found in the observed images of MgCl 2 particles. The observation of the structure of MgCl2-supported Ziegler ca talysts shows that the MgCl2 crystals are severely deformed by the processe s of catalyst preparation. Due to the preparation procedure used the struct ure of the catalyst changes from crystalline to amorphous.