The role of the intrinsic surface state (Iz = 0) in the decay of the first
image state (n = 1) at the (111) surface of copper is investigated. Inelast
ic linewidths are evaluated from the knowledge of the imaginary part of the
electron self energy, which we compute, within the GW approximation of the
many-body theory, by going beyond a free-electron description of the metal
surface. Single-particle wave functions are obtained by solving the Schrod
inger equation with a realistic one-dimensional model potential, and depart
ure of the motion along the surface from free-electron behavior is consider
ed through the introduction of the effective mass. The decay of the first i
mage state of Cu(lll) into the intrinsic surface state is found to result i
n a linewidth that represents 40% of the total linewidth. The dependence of
linewidths on the momentum of the image state parallel to the surface is a
lso investigated. [S0163-1829(99)09415-1].