Characterization of poly(2-propenoyl chloride) by nuclear magnetic resonance spectroscopy

Authors
Gaillard, C Camps, M
Citation
C. Gaillard et M. Camps, Characterization of poly(2-propenoyl chloride) by nuclear magnetic resonance spectroscopy, POLYMER, 40(17), 1999, pp. 4961-4964
Citations number
10
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER
ISSN journal
00323861 → ACNP
Volume
40
Issue
17
Year of publication
1999
Pages
4961 - 4964
Database
ISI
SICI code
0032-3861(199908)40:17<4961:COPCBN>2.0.ZU;2-1
Abstract
A device to obtain the nuclear magnetic resonance (NMR) spectra of poly(2-p ropenoyl chloride) (PPC) avoiding any contact with the room moisture is des cribed. The H-1 and C-13 NMR spectra of PPC in THF-d(8) solution are thus o btained. The distribution of meso and racemic dyads inferred from the integ ration of different H-1 NMR signals is: (m) = 0.45 and (r) = 0.55. (C) 1999 Elsevier Science Ltd. All rights reserved.