NGC 6537 is an unusually high excitation point symmetric planetary nebula w
ith a rich spectrum. Its kinematical structures are of special interest. We
are here primarily concerned with the high resolution spectrum as revealed
by the Hamilton echelle Spectrograph at Lick Observatory (resolution appro
ximate to 0.2 Angstrom) and supplemented by UV and near-UV data. These exte
nsive data permit a determination of interstellar extinction, plasma diagno
stics, and ionic concentrations. The photoionization models that have been
used successfully for many planetary nebulae are not entirely satisfactory
here. The plasma electron temperature of a photoionization model cannot muc
h exceed 20,000 K, but plasma diagnostics show that regions emitting radiat
ion of highly ionized atoms such as [NeIV] and [NeV] are much hotter, showi
ng that shock excitation must be important, as suggested by the remarkable
kinematics of this object. Hence, instead of employing a strict photoioniza
tion model, we are guided by the nebular diagnostics, which reveal how elec
tron temperature varies with ionization potential and accommodates density
effects. The predictions of the photoionization model may be useful in esti
mating ionization correction factor, In effect, we have estimated the chemi
cal composition by using both photoionization and shock considerations.