Improvement of the process for separating gadolinium and europium by europium cementation

Citation
Vm. Lebedev et al., Improvement of the process for separating gadolinium and europium by europium cementation, RADIOCHEMIS, 41(2), 1999, pp. 132-135
Citations number
2
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RADIOCHEMISTRY
ISSN journal
10663622 → ACNP
Volume
41
Issue
2
Year of publication
1999
Pages
132 - 135
Database
ISI
SICI code
1066-3622(199903/04)41:2<132:IOTPFS>2.0.ZU;2-#
Abstract
The content of process impurities washed out in the course of dissolution o f irradiated europim targets of various constructions was determined. The i nfluence of these impurities on europium cementation was studied. The use o f a quartz powder as the filler instead of foam alundum accelerates and sim plifies gadolinium recovery, Complete replacement of europium amalgam in th e course of cementation in the separator of a semicounterflow apparatus inc reased the degree of gadolinium recovery in one cementation cycle by a fact or of 5-6. A unit for industrial separation of europium and gadolinium by e uropium cementation was developed. The unit consists of a semicounterflow a pparatus with a mobile mercury phase, a feeder for process solutions, and a worm feeder for mercury. The process parameters of this unit were determin ed. These improvements decreased the number of cementation cycles necessary for recovering Gd-153 with required purity and reduced the content of euro pium radionuclides in the gadolinium preparation.