R. Saiz-pardo et al., Systematic theoretical studies of the Schottky barrier control by passivating atomic intralayers, SURF SCI, 426(1), 1999, pp. 26-37
The effect of different atomic intralayers on the Schottky barrier height p
hi(bn) of covalent and ionic semiconductors has been studied theoretically.
The following cases have been analysed: H/Si(111), Sb/Si(111), S/Ge(100),
H/GaAs(110), Sb/GaAs(110) and As/GaAs(110). Our results show that phi(bn) i
s reduced by all the intralayers and that this reduction increases with the
intralayer electronegativity and the semiconductor ionicity. These results
are explained by the chemical interaction between the adsorbed metal orbit
als and the new levels associated with the passivating layer. This interact
ion shifts the semiconductor charge neutrality level to higher energies and
, consequently, reduces the Schottky barrier height. (C) 1999 Elsevier Scie
nce B.V. All rights reserved.