Superactive iodination reagent on a base of iodine chloride and silver sulfate

Authors
Chaikovski, VK Kharlova, TS Filimonov, VD Saryucheva, TA
Citation
Vk. Chaikovski et al., Superactive iodination reagent on a base of iodine chloride and silver sulfate, SYNTHESIS-S, (5), 1999, pp. 748-750
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
5
Year of publication
1999
Pages
748 - 750
Database
ISI
SICI code
0039-7881(199905):5<748:SIROAB>2.0.ZU;2-G
Abstract
After reaction of ICI and Ag2SO4 in sulfuric acid and separation of resulti ng AgCl a stable solution is formed, containing very active forms of electr ophilic iodine. This solution has a powerful iodination ability with respec t to aromatic compounds. Deactivated arenes are iodinated easily and in mil d conditions by action of this new reagent in generally good yields of the iodoarenes.