A general synthesis of thiophosphates containing an alpha,beta-unsaturatedcarbonyl moiety

Authors
Dybowski, P Koprowski, M Maciagiewicz, I Skowronska, A
Citation
P. Dybowski et al., A general synthesis of thiophosphates containing an alpha,beta-unsaturatedcarbonyl moiety, SYNTHESIS-S, (5), 1999, pp. 844-848
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
5
Year of publication
1999
Pages
844 - 848
Database
ISI
SICI code
0039-7881(199905):5<844:AGSOTC>2.0.ZU;2-K
Abstract
The O-silylated dienolates of alpha,beta-unsaturated ketones and aldehydes can be thiophosphorylated using O,O-dialkyl chlorothiophosphonates and O,O- dialkyl bromodithiophosphonates to give a new class of compounds thio- and dithiophosphates 1-4 in high yield.