SYNTHESIS AND CHARACTERIZATION OF BENZYL BETA-CYCLODEXTRINS USED AS GC STATIONARY PHASES

Authors
XIAO DQ CHE BQ FU RN GU JL WEN YX LING Y ZHANG HB
Citation
Dq. Xiao et al., SYNTHESIS AND CHARACTERIZATION OF BENZYL BETA-CYCLODEXTRINS USED AS GC STATIONARY PHASES, Chromatographia, 44(7-8), 1997, pp. 393-398
Citations number
14
Categorie Soggetti
Chemistry Analytical","Biochemical Research Methods
Journal title
Chromatographia → ACNP
ISSN journal
00095893
Volume
44
Issue
7-8
Year of publication
1997
Pages
393 - 398
Database
ISI
SICI code
0009-5893(1997)44:7-8<393:SACOBB>2.0.ZU;2-D
Abstract
Heptakis(2,6-di-O-benzyl)-beta-CD (I), heptakis(2,6-di-O-benzyl-3-O-pe ntyl)-beta-CD (II), heptakis(2,6-di-O-benzyl - 3-O-methyl)-beta-CD (II I) and heptakis(2,6-di-O-benzyl-3-O-acetyl)-beta-CD (IV) derivatives w ere synthesized and identified. Their thermal stabilities were tested using PyGC. These CD derivatives are stable up to 300 degrees C and su itable for use as gas chromatographic stationary phases. The fused sil ica capillary columns coated with heptakis (2,6-di-O-benzyl-3-O-methyl )-beta-CD and heptakis(2,6-di-O-benzyl-3-O-pentyl)-beta-CD showed exce llent chromatographic properties in separating positional isomers.