Synthetic isoprene rubber (SIR) is chlorinated in a gas-liquid SIR-Cl-2-CCl
4-Ar mixture in a flow reactor operating in a cyclic mode. To attain homoge
neous chlorination (the time of continuous contact between macromolecules a
nd the chlorine-containing gaseous phase is much shorter than the reaction
time), a special device turbulizing the gas-liquid flow was used in combina
tion with chlorine dilution with an inert gas.