Isoprene rubber chlorination in a gas-liquid system with turbulent mixing

Citation
Bl. Rytov et al., Isoprene rubber chlorination in a gas-liquid system with turbulent mixing, CHEM PHYS R, 17(11), 1999, pp. 2119-2123
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS REPORTS
ISSN journal
10741550 → ACNP
Volume
17
Issue
11
Year of publication
1999
Pages
2119 - 2123
Database
ISI
SICI code
1074-1550(1999)17:11<2119:IRCIAG>2.0.ZU;2-X
Abstract
Synthetic isoprene rubber (SIR) is chlorinated in a gas-liquid SIR-Cl-2-CCl 4-Ar mixture in a flow reactor operating in a cyclic mode. To attain homoge neous chlorination (the time of continuous contact between macromolecules a nd the chlorine-containing gaseous phase is much shorter than the reaction time), a special device turbulizing the gas-liquid flow was used in combina tion with chlorine dilution with an inert gas.