Kinetics and mechanism of 2,6-di-tert-butylhydroquinone oxidation in solution

Authors
Shanina, EL Zaikov, GE Belyakov, BA
Citation
El. Shanina et al., Kinetics and mechanism of 2,6-di-tert-butylhydroquinone oxidation in solution, CHEM PHYS R, 17(11), 1999, pp. 2129-2136
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS REPORTS
ISSN journal
10741550 → ACNP
Volume
17
Issue
11
Year of publication
1999
Pages
2129 - 2136
Database
ISI
SICI code
1074-1550(1999)17:11<2129:KAMO2O>2.0.ZU;2-Z
Abstract
The kinetics of 2, 6-di-tert-butylhydroquinone oxidation is studied by spec trophotometry and pressure monitoring in a closed vessel. A kinetic mechani sm of the oxidation reaction is proposed the key step in which is the react ion of phenoxyl radical with oxygen.