Aj. Simaan et al., Characterization of a nonheme mononuclear peroxoiron(III) intermediate by UV Vis and EPR spectroscopy and mass spectrometry, EUR J INORG, (6), 1999, pp. 993-996
Some nonheme hydroperoxoiron(III) species have been recently characterized
by several groups. The reported examples were obtained by adding H2O2 in ex
cess to an Fe-II complex with a neutral polypyridine ligand. We show here t
hat on deprotonation, the purple low-spin hydroperoxoiron(III) complex [(LF
eOOH)-Fe-5-O-III](2+) [L-5 = N-methyl-N,N',N'-tris(2-pyridylmethyl)ethane-1
,2-diamine] gives a blue high spin species which we characterized as the et
a(2)-peroxoiron(III) species [(LFeO2)-Fe-5-O-III](+). It seems that with su
ch an auxiliary ligand, the hydroperoxo group is acidic in contrast with it
s basicity when it is coordinated to a heme group.