Lx. Cao et al., A STRUCTURAL INVESTIGATION OF HIGH-QUALITY EPITAXIAL PB(ZR,TI)O-3 THIN-FILMS, Journal of physics. D, Applied physics, 30(10), 1997, pp. 1455-1458
The Pb(Zr0.53Ti0.47)O-3 (PZT 53/47) and Pb(Zr0.20Ti0.80)O-3 (PZT 20/80
) films deposited on (100)SrTiO3 substrates by RF magnetron sputtering
are single-phase epitaxial films. In order to prevent large thermal s
tresses being induced in the films during the preparation process, the
PZT films were cooled slowly through the Curie temperature. Scanning
electron microscopy (SEM) showed that the PZT 53/47 film had a pyramid
structure on its surface, whereas the PZT 20/80 film had a smooth sur
face without any observable features. Transmission electron microscopy
(TEM) observations showed similar features: the PZT 53/47 film had a
coarse columnar structure, whereas the PZT 20/80 film had a fine cryst
alline structure; this is due to the better lattice matching in the la
tter.