The effects of system composition and processing conditions on the formatio
n of mutagenic reaction products (ethylnitrolic acid and 1,4-dinitro -2-met
hylpyrrole) from the reaction of potassium sorbate and sodium nitrite were
investigated in model systems resembling meat products, using gas chromatog
raphy-mass spectrometry and high performance liquid chromatography. It was
observed that 1,4-dinitro-2-methylpyrrole formation was precluded when asco
rbic acid or cysteine were present. Ethylnitrolic acid was detected in all
systems studied after heating at 35 or 60 degrees C. Results highlight the
need for minimizing the combined use of nitrites and sorbates in food produ
cts. (C) 1999 Published by Elsevier Science Ltd on behalf of the Canadian I
nstitute of Food Science and Technology. All rights reserved.