A regioselective 1,3-dipolar cycloaddition of 2-arylidene-1-tetralones with DPNI

Citation
M. Shanmugasundaram et al., A regioselective 1,3-dipolar cycloaddition of 2-arylidene-1-tetralones with DPNI, HETEROAT CH, 10(4), 1999, pp. 331-336
Citations number
34
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
10
Issue
4
Year of publication
1999
Pages
331 - 336
Database
ISI
SICI code
1042-7163(1999)10:4<331:AR1CO2>2.0.ZU;2-S
Abstract
Synthesis of a series of novel 1,3-diphenyl-4-arylspiropyrazolines[5, 2(1)] - 1(1)-tetralones has been accomplished in good yield by regioselective 1,3 -dipolar cycloaddition of diphenylnitrilimine with (E)-2-arylidene-1-tetral ones. X-ray crystal structure analysis of one of the products 4b confirms t he structure and the regiochemistry of cycloatddition. (C) 1999 John Wiley & Sons, Inc.