Formation of ultrafinely dispersed oxide and metal phases by electron-beamirradiation of cellulose modified with transition metal salts

Citation
Vb. Komarov et al., Formation of ultrafinely dispersed oxide and metal phases by electron-beamirradiation of cellulose modified with transition metal salts, HIGH ENERG, 33(3), 1999, pp. 161-164
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
HIGH ENERGY CHEMISTRY
ISSN journal
00181439 → ACNP
Volume
33
Issue
3
Year of publication
1999
Pages
161 - 164
Database
ISI
SICI code
0018-1439(199905/06)33:3<161:FOUDOA>2.0.ZU;2-V
Abstract
Radiation-thermal transformations of cellulose modified with iron and other transition metal salts were studied. It was shown that electron beam irrad iation at a dose rate of greater than or equal to 9.0 kGy/s results in inte nse heating of the material. At an absorbed dose of 400 kGy, a temperature of 650 K is attained. Under these conditions, the pyrolysis of cellulose ta kes place and ultrafinely dispersed metal particles and nonstoichiometric o xides in the pyrophoric state are produced. The mechanism of the transforma tions is discussed.