Disproportionation, internal redox and comproportionation in the reaction of Hg-2(2+) with WS42-: synthesis and structure of a novel mixed crystal, (PPh4)(2)[{Hg-2(S)(2)}(0.333)(W2S6)(0.666)]

Authors
Pradhan, R Piro, OE Castellano, EE Bhattacharyya, R
Citation
R. Pradhan et al., Disproportionation, internal redox and comproportionation in the reaction of Hg-2(2+) with WS42-: synthesis and structure of a novel mixed crystal, (PPh4)(2)[{Hg-2(S)(2)}(0.333)(W2S6)(0.666)], INORG CH C, 2(5), 1999, pp. 173-175
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
5
Year of publication
1999
Pages
173 - 175
Database
ISI
SICI code
1387-7003(199905)2:5<173:DIRACI>2.0.ZU;2-Z
Abstract
An equimolar mixture of (PPh4)(2) [Hg(CN)(2)Cl-2] and metallic mercury reac ts with WS42- affording a yellow complex which on structural characterisati on was found to be a solid state mixture (PPh4)(2)[(Hg-2(S-2))(0.333)(W2S6) (0.666)]. (C) 1999 Elsevier Science S.A. All rights reserved.