OXIDATIVE ADDITION OF A C-SE BOND TO A PT-II CENTER - CONTRASTING REACTIONS OF [MCL2(PHCN)(2)] (M=PD, PT) WITH CYCLOHEPTENO-1,4-DISELENIN

Authors
BATES CM KHANNA PK MORLEY CP DIVAIRA M
Citation
Cm. Bates et al., OXIDATIVE ADDITION OF A C-SE BOND TO A PT-II CENTER - CONTRASTING REACTIONS OF [MCL2(PHCN)(2)] (M=PD, PT) WITH CYCLOHEPTENO-1,4-DISELENIN, Chemical communications, (10), 1997, pp. 913-914
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
10
Year of publication
1997
Pages
913 - 914
Database
ISI
SICI code
1359-7345(1997):10<913:OAOACB>2.0.ZU;2-5
Abstract
The reaction of cyclohepteno-1,4-diselenin 1 with [PtCl2(PhCN)(2)] pro ceeds via unprecedented oxidative addition of a C-Se bond to yield a p latinum(Iv) product, whose novel dimeric structure has been determined by X-ray crystallography; by contrast, 1 reacts with [PdCl2(PhCN)(2)] to form trans-[PdCl2L2] (L=1).