ENANTIOSELECTIVE SYNTHESIS OF HOMOALLYLIC ALCOHOLS USING (E)-BUT-2-ENYL-TRICHLOROSILANE AND CHIRAL DIAMINES

Authors
ANGELL RM BARRETT AGM BRADDOCK DC SWALLOW S VICKERY BD
Citation
Rm. Angell et al., ENANTIOSELECTIVE SYNTHESIS OF HOMOALLYLIC ALCOHOLS USING (E)-BUT-2-ENYL-TRICHLOROSILANE AND CHIRAL DIAMINES, Chemical communications, (10), 1997, pp. 919-920
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
10
Year of publication
1997
Pages
919 - 920
Database
ISI
SICI code
1359-7345(1997):10<919:ESOHAU>2.0.ZU;2-R
Abstract
Condensation of aromatic aldehydes and (E)-but-2-enyltrichlorosilane i n the presence of (+)-4-(2-methylpropyl)-2-(2-pyridinyl)-2-oxazoline g ives the corresponding homoallylic alcohols in excellent anti-diastere oselectivity (> 99%)and good enantioselectivity (36-74%).