TANDEM OXA-MICHAEL ADDITION-S(N)2' SUBSTITUTION OF 4-CHLOROBUT-2-YN-1-OL WITH NITROALKENES - A TOTAL ALLYLIC 1,3-STRAIN-CONTROLLED DIASTEREOSELECTIVE SYNTHESIS OF 3-VINYLIDENETETRAHYDROFURANS

Authors
DULCERE JP DUMEZ E
Citation
Jp. Dulcere et E. Dumez, TANDEM OXA-MICHAEL ADDITION-S(N)2' SUBSTITUTION OF 4-CHLOROBUT-2-YN-1-OL WITH NITROALKENES - A TOTAL ALLYLIC 1,3-STRAIN-CONTROLLED DIASTEREOSELECTIVE SYNTHESIS OF 3-VINYLIDENETETRAHYDROFURANS, Chemical communications, (10), 1997, pp. 971-972
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
10
Year of publication
1997
Pages
971 - 972
Database
ISI
SICI code
1359-7345(1997):10<971:TOASO4>2.0.ZU;2-M
Abstract
(BuOK)-O-t-promoted reaction of 4-chlorobut-2-yn-1-ol 1 with nitroalke nes 2 affords 3-vinylidenetetrahydrofurans 3 in good yields with total diastereoselectivity.