Adsorption behavior and separation of vanadium(V), molybdenum(VI), and rhenium(VII) ions on crosslinked polymers containing acrylic acid derivative moieties
Bl. Rivas et al., Adsorption behavior and separation of vanadium(V), molybdenum(VI), and rhenium(VII) ions on crosslinked polymers containing acrylic acid derivative moieties, J APPL POLY, 73(3), 1999, pp. 369-376
The radical polymerization of [2-(acryloyloxy)ethyl] trimethylammonium meth
yl sulfate and [3-(methacryloylamino)propyl] trimethylammonium chloride by
using ammonium peroxydisulfate as initiator and N,N'-methylene-bis-acrylami
de as crosslinker agent at 70 degrees C for 17 h was carried out. The cross
linker agent in the feed ranged between 2 and 6 mol %. The resins were comp
letely insoluble in water and characterized by elemental analysis and FTIR
spectroscopy. The metal ion binding capacity of these resins with V(V), Mo(
VI), and Re(VII) were investigated using the batch equilibrium type. The pH
, but not the crosslinking percentage in the feed, influenced the retention
capacity of the resin, particularly for V(V) and Re(VII). Thus, at pH 1 on
ly < 15% of V(V) was retained, but at pH 3 higher than 97% of V(V) was adso
rbed. The resin-ion equilibrium was achieved between 15 min and 2 h dependi
ng on the resin, ion, and crosslinking degree. According to the pH, it is p
ossible separate Re(VII) and Mo(VI) from V(V) at pH 1.0. To reuse the resin
s, the ions were stripped by using HCl, H2SO4, and Na2CO3 at different conc
entrations. (C) 1999 John Wiley & Sons, Inc.