Rotationally resolved differential scattering cross sections for the reaction F+para-H-2 (v=0,j=0)-> HF(v '=2,3,j ')+H

Citation
M. Baer et al., Rotationally resolved differential scattering cross sections for the reaction F+para-H-2 (v=0,j=0)-> HF(v '=2,3,j ')+H, J CHEM PHYS, 110(21), 1999, pp. 10231-10234
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
110
Issue
21
Year of publication
1999
Pages
10231 - 10234
Database
ISI
SICI code
0021-9606(19990601)110:21<10231:RRDSCS>2.0.ZU;2-G
Abstract
Time-of-flight spectra of HF products in the v' = 2 vibrational state from reactive scattering of F atoms from para-H-2 exhibit at least four smaller peaks which are assigned to the rotational states j' = 7, 8, 9, and 10. The center-of-mass rotational distributions are in good agreement with accurat e quantum mechanical and approximate coupled states calculations. (C) 1999 American Institute of Physics. [S0021-9606(99)01221-0].