FORMATION OF TIN(IV) ADDUCTS BY THE REACTIONS OF TRI(N-OCTYL)PHOSPHINE OXIDE WITH TIN(II) HALIDES - A SPECTRAL STUDY

Authors
SELVARAJU R PANCHANATHESWARAN K
Citation
R. Selvaraju et K. Panchanatheswaran, FORMATION OF TIN(IV) ADDUCTS BY THE REACTIONS OF TRI(N-OCTYL)PHOSPHINE OXIDE WITH TIN(II) HALIDES - A SPECTRAL STUDY, Polyhedron, 16(15), 1997, pp. 2621-2623
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
15
Year of publication
1997
Pages
2621 - 2623
Database
ISI
SICI code
0277-5387(1997)16:15<2621:FOTABT>2.0.ZU;2-4
Abstract
The reactions of SnX2 (X = Cl,Br) with tri(n-octyl)phosphine oxide (TO PO) under aerobic conditions yielded the oxidative addition products o f the stoichiometry SnX4 . 2TOPO, as inferred by their mass spectra. T he P-31 NMR and Sn-119 NMR of the products indicated the presence of c is and trans isomers in solution. (C) 1997 Elsevier Science Ltd.