Synthesis and characterization of new binuclear Co(0) complexes with diphosphinoamine ligands. A potential approach for asymmetric Pauson-Khand reactions

Authors
Gimbert, Y Robert, F Durif, A Averbuch, MT Kann, N Greene, AE
Citation
Y. Gimbert et al., Synthesis and characterization of new binuclear Co(0) complexes with diphosphinoamine ligands. A potential approach for asymmetric Pauson-Khand reactions, J ORG CHEM, 64(10), 1999, pp. 3492-3497
Citations number
33
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
64
Issue
10
Year of publication
1999
Pages
3492 - 3497
Database
ISI
SICI code
0022-3263(19990514)64:10<3492:SACONB>2.0.ZU;2-1
Abstract
The synthesis bf P-N-P bidentate ligands and the evaluation, based on IR an d X-ray data, of their pi-acceptor properties in the complexes a derived fr om phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition , the reactivity of these complexes in the Pauson-Khand reaction has been e xamined.