Intramolecular electron transfer in mixed-valence complexes [(NH3)(5)Ru-L-Ru(NH3)(5)](5+) (L = N-2, pyz, pym, 4,4 '-bipy, bpa)

Authors
Sizova, OV Baranovskii, VI Panin, AI Ivanova, NV
Citation
Ov. Sizova et al., Intramolecular electron transfer in mixed-valence complexes [(NH3)(5)Ru-L-Ru(NH3)(5)](5+) (L = N-2, pyz, pym, 4,4 '-bipy, bpa), J STRUCT CH, 39(4), 1998, pp. 471-479
Citations number
38
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
39
Issue
4
Year of publication
1998
Pages
471 - 479
Database
ISI
SICI code
0022-4766(199807/08)39:4<471:IETIMC>2.0.ZU;2-H
Abstract
The dynamics of the intramolecular electron transfer from Ru(II) to Ru(III) in binuclear mixed-valence complexes [(NH3)(5)Ru-L-Ru(NH3)(5)](5+) (L = N- 2, pyz, bipy, pym, bpa) is analyzed by the semiempirical CINDO + CI method.