Crystal structure of polymorphous modifications of Tm2S3 and related compounds

Citation
Sv. Borisov et al., Crystal structure of polymorphous modifications of Tm2S3 and related compounds, J STRUCT CH, 39(4), 1998, pp. 543-548
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
39
Issue
4
Year of publication
1998
Pages
543 - 548
Database
ISI
SICI code
0022-4766(199807/08)39:4<543:CSOPMO>2.0.ZU;2-9
Abstract
The role of symmetry in crystal structure formation is revealed for the pol ymorphous modifications of Tm2S3 and related compounds Tm15S22, Tm5S7, and Tm8S11 using the procedure of selecting and analyzing close-packed planes w ith cationic, anionic, and combined motifs. The laws of mutual agreement be tween the cation and anion matrices determining the size of the unit cells are examined and relationships between the specific cation volumes and symm etry are traced.