Crystal and molecular structure of zinc(II) di-n-propyldithiocarbamate complexes with 2,2 '-bipyridyl and 1,10-phenanthroline

Authors
Glinskaya, LA Klevtsova, RF Berus, EI Zemskova, SM Larionov, SV
Citation
La. Glinskaya et al., Crystal and molecular structure of zinc(II) di-n-propyldithiocarbamate complexes with 2,2 '-bipyridyl and 1,10-phenanthroline, J STRUCT CH, 39(4), 1998, pp. 559-566
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
39
Issue
4
Year of publication
1998
Pages
559 - 566
Database
ISI
SICI code
0022-4766(199807/08)39:4<559:CAMSOZ>2.0.ZU;2-C
Abstract
The structure of Zn[S2CN(n-C3H7)(2)](2)(2,2'-Bipy) and Zn[S2CN(n-C3H7)(2)]( 2)Phen was determined by X-ray diffraction analysis (CAD-4 diffractometer, MoKalpha radiation) for the monoclinic (a = 9.646, b = 20.978, c = 14.555 A ngstrom; beta = 94.95 degrees; Z = 4;space group P2(1)/n) and orthorhombic (a = 18.621, b = 14.701, c = 10.676 Angstrom; Z = 4; space group Aba2) crys tals. The structures consist of discrete monomer molecules packed with the aid of S ... H-C and C ... H-C hydrogen bonds and van der Waals interaction s.