N. Favrot et al., Cold compaction and solid-state sintering of WC-Co-based structures: Experiments and modeling, J AM CERAM, 82(5), 1999, pp. 1153-1161
Cold compaction (200-1900 MPa) and sintering (1250 degrees-1350 degrees C)
of cermets based on WC-Co were experimentally studied using die compaction,
cold isostatic pressing, sintering, and creep tests. Two different-sized W
C powders were used. The cobalt content varied over a range of 10-30 wt%. C
old-compaction behavior has been described by using a Cam-Clay model. Die-w
all friction was measured by using green powder compacts that had different
aspect ratios. Friction coefficients were 0.28-0.85, depending on the WC p
article size and cobalt content. Simple constitutive equations have been us
ed to model the high-temperature behavior (sintering and creep). The consti
tutive equations were implemented in a finite-element program to model the
compaction, ejection, and sintering of bilayer structures that had differen
t cobalt contents. The model can represent the effect of die-wall friction
on the average density, as well as deformation inside the green compact. De
nsity gradients were generated; they were revealed during sintering, becaus
e the compact does not deform homogeneously. Simulation also can be used to
evaluate deformations that are induced by sintering.