Peroxo-oxalate preparation of doped barium titanate

Citation
S. Van Der Gijp et al., Peroxo-oxalate preparation of doped barium titanate, J AM CERAM, 82(5), 1999, pp. 1175-1180
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
ISSN journal
00027820 → ACNP
Volume
82
Issue
5
Year of publication
1999
Pages
1175 - 1180
Database
ISI
SICI code
0002-7820(199905)82:5<1175:PPODBT>2.0.ZU;2-P
Abstract
The peroxo-oxalate complexation method is a method that can be used for the preparation of doped barium titanate, In this paper we focus on BaTi0.91Zr 0.09O3, which can be used for discharge capacitors in lamp starters, The pr eparation method described here is based on the complexation and subsequent precipitation in basic environment of Ba, Ti, and Zr ions with hydrogen pe roxide and oxalate, The influence of several process parameters, like preci pitation temperature and pH, on powder properties is described. A single-ph ase perovskite crystal structure is obtained after calcination starting fro m a chloride precursor solution using a precipitation temperature of 40 deg rees C and a pH of 9. Because the peroxo-oxalate process starts with inexpe nsive chlorides and is performed in air, the peroxo-oxalate process is suit able for the commercial production of doped barium titanate.