[Me2Si] Ansa bridged complexes of permethyltitanocene: synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character
H. Lee et al., [Me2Si] Ansa bridged complexes of permethyltitanocene: synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character, J CHEM S DA, (9), 1999, pp. 1365-1368
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
A series of permethylated [Me2Si] ansa bridged titanocene complexes has bee
n synthesized and structurally characterized by X-ray diffraction; the dial
kyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination
of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me3CH
2)]TiR.