[Me2Si] Ansa bridged complexes of permethyltitanocene: synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character

Authors
Lee, H Bonanno, JB Hascall, T Cordaro, J Hahn, JM Parkin, G
Citation
H. Lee et al., [Me2Si] Ansa bridged complexes of permethyltitanocene: synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character, J CHEM S DA, (9), 1999, pp. 1365-1368
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
9
Year of publication
1999
Pages
1365 - 1368
Database
ISI
SICI code
0300-9246(19990507):9<1365:[ABCOP>2.0.ZU;2-R
Abstract
A series of permethylated [Me2Si] ansa bridged titanocene complexes has bee n synthesized and structurally characterized by X-ray diffraction; the dial kyl complexes [Me2Si(C5Me4)]TiR2 are thermally unstable towards elimination of alkane (RH), thereby yielding fulvene derivatives [Me2Si(C5Me4)(C5Me3CH 2)]TiR.