The first evidence for activation of exogenous O-2 on a vanadium(IV) center: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate

Authors
Kosugi, M Hikichi, S Akita, M Moro-oka, Y
Citation
M. Kosugi et al., The first evidence for activation of exogenous O-2 on a vanadium(IV) center: synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)borate, J CHEM S DA, (9), 1999, pp. 1369-1371
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
9
Year of publication
1999
Pages
1369 - 1371
Database
ISI
SICI code
0300-9246(19990507):9<1369:TFEFAO>2.0.ZU;2-L
Abstract
Reaction of a vanadium(IV) hydroxo complex bearing hydrotris(3,5-diisopropy lpyrazol-1-yl)borate (Tp(Pr12)) with O-2 results in reductive O-2 activatio n to give Tp(Pr12)V(V)(O)(eta(2)-O-2)(L); the first example of the formatio n of a peroxo vanadium complex from molecular oxygen.