T. Sekino et al., REDUCTION AND SINTERING OF A NICKEL-DISPERSED-ALUMINA COMPOSITE AND ITS PROPERTIES, Journal of the American Ceramic Society, 80(5), 1997, pp. 1139-1148
High-density nickel-dispersed-alumina (Al2O3/nickel) composites with s
uperior mechanical properties were obtained by the hydrogen reduction
and the hot pressing of alumina-nickel oxide (Al2O3/NiO) mixed powders
. The mixtures were prepared by using NiO or nickel nitrate (Ni(NO3)(2
) . nH(2)O) as a dispersion source of nickel metal. Microstructural in
vestigations of the composite fabricated using nitrate powder revealed
that fine nickel particles, approximate to 100 nm in diameter, disper
sed homogeneously at the matrix grain boundaries, forming the intergra
nular nanocomposite. High strength (>1 GPa) and high-temperature hardn
ess were registered for the composite that contained a small amount of
nickel dispersion. The ferromagnetic properties of nickel, such as hi
gh coercive force, were observed, because of the fine magnetic dispers
ions, which indicates a functional value of structural composites.