Increasing availability and reliability of ultra-short pulse laser systems
is opening up the possibility of using such lasers for ablation and structu
ring of dielectrics and other materials (e.g. metals) which cannot be struc
tured with high micro-metre precision using standard ns laser systems. In t
his chapter the advantage, of visible (800 nm) ultra-short laser pulses for
micro-structuring of high band gap materials is discussed. Different pheno
mena are observed, related to three fluence regimes. (i) Fluence " damage t
hreshold fluence (F-th) In this regime it is possible to produce long chann
els with a high aspect ratio and little residual damage and stress in the m
aterial. (ii) Fluence = F-th Here, two distinct ablation phases can be obse
rved. A "gentle" and a "strong" ablation phase. The gentle phase leads to c
ontrolled melting and vaporisation of material, sometimes accompanied by ri
pple formation on the surface. At higher laser intensities (or after a suff
icient number of incubation pulses) the strong ablation phase is observed w
hich we relate to phase explosion. (iii) Fluence < F-th Self-focusing of th
e laser light due to the Ken effect can occur in the dielectric materials f
or ps pulses. This leads to the possibility of direct writing of micro-stru
ctures in the material bulk without producing damage on the entrance or exi
t surfaces. Manipulating the laser pulse width and/or pulse energy can cont
rol the position of the structures caused in the bulk. Similar non-linear o
ptical effects are responsible for material removal from the exit surface o
f the material to leave extremely smooth well-defined micro-metre sized con
e-shaped holes.