T. Goto et al., Effect of oxygen gas addition on preparation of iridium and platinum filmsby metal-organic chemical vapor deposition, MATER T JIM, 40(3), 1999, pp. 209-213
The effect of oxygen gas addition on deposition rates, composition and micr
ostructure was investigated in preparing Ir and Pt films by metal-organic c
hemical vapor deposition using Ir- and Pt-acetylacetonate precursors. Witho
ut the addition of oxygen gas, 20 mass% of carbon at most was contained in
the films. The carbon was amorphous, surrounding metal particles of several
nanometers in diameter. The addition of oxygen gas is effective in obtaini
ng carbon-free Ir and Pt films, and the films grow epitaxially on MgO and s
apphire single crystal substrates.