Ship-in-bottle synthesis of palladium carbonyl complexes in NaY and NaX zeolites via the direct carbonylation of Pd(NH3)(4)(2+)

Authors
Drozdova, L Novakova, J Schulz-Ekloff, G Jaeger, NI
Citation
L. Drozdova et al., Ship-in-bottle synthesis of palladium carbonyl complexes in NaY and NaX zeolites via the direct carbonylation of Pd(NH3)(4)(2+), MICROP M M, 28(3), 1999, pp. 395-403
Citations number
45
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
MICROPOROUS AND MESOPOROUS MATERIALS
ISSN journal
13871811 → ACNP
Volume
28
Issue
3
Year of publication
1999
Pages
395 - 403
Database
ISI
SICI code
1387-1811(199905)28:3<395:SSOPCC>2.0.ZU;2-S
Abstract
Neutral palladium carbonyl complexes in NaX and NaY zeolites were prepared via the direct carbonylation of [Pd(NH3)(4)](2+) complexes at room temperat ure using the ability of noble-metal complexes to catalyze the low-temperat ure water-gas shift reaction for the reduction of metal cations. The kineti cs of carbonylation as well as decarbonylation processes were monitored by in situ FTIR spectroscopy. Both reactions are faster in NaX than in NaY. Th e higher reactivity in NaX is attributed to the higher density of charges a s compared to NaY. (C) 1999 Elsevier Science B.V. All rights reserved.