A thiophosphorylated hemicryptophane: structure of the toluene inclusion complex

Citation
I. Gosse et al., A thiophosphorylated hemicryptophane: structure of the toluene inclusion complex, NEW J CHEM, 23(5), 1999, pp. 545-548
Citations number
13
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
23
Issue
5
Year of publication
1999
Pages
545 - 548
Database
ISI
SICI code
1144-0546(199905)23:5<545:ATHSOT>2.0.ZU;2-5
Abstract
The reaction of the tri-(benzaldehyde)-substituted cyclotriveratrylene 6 wi th phosphotrihydrazide under high dilution conditions gives rise to the nov el thiophosphorylated hemicryptophane 1. 1 is representative of a new famil y of molecular receptors providing a molecular cavity available for neutral and charged guests. In the crystal, compound 1 encapsulates one toluene mo lecule.