The existence of three-body resonances in the molecular ion pp pi has been
shown by means of a variational calculation in Jacobi coordinates. The rela
tivistic and strong-force corrections to the Coulombic binding energies and
the decay widths of the resonances have been calculated. We consider two m
echanisms that supply the p pi atom with large kinetic energies before the
moment of pion absorption by the proton, with significant impact on the int
erpretation of experiments measuring the mass difference m(pi)- (-)m(pi 0)
from pion absorption in pionic atoms. These mechanisms are (a) the formatio
n and subsequent Coulomb decay of the metastable pp pi states and (b) pion
absorption from the molecular pp pi state, giving, respectively, a discrete
or a continuous distribution of kinetic energies of the resulting p pi ato
ms. [S1050-2937(99)05005 1].