Temperature difference between bulk and surface transition in freely suspended smectic films

Citation
D. Schlauf et al., Temperature difference between bulk and surface transition in freely suspended smectic films, PHYS REV E, 59(5), 1999, pp. 6188-6191
Citations number
43
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
59
Issue
5
Year of publication
1999
Part
B
Pages
6188 - 6191
Database
ISI
SICI code
1063-651X(199905)59:5<6188:TDBBAS>2.0.ZU;2-5
Abstract
We report an ellipsometric study of freely suspended films of a chiral liqu id-crystal compounded possessing the phase sequence smectic-C-smectic-A-iso tropic with a very broad.(67 K) smectic-A phase range. We observe a smectic -C-smectic-A surface transition which is, situated more than 60 K above the bulk smectic-C-smectic-A transition temperature. Possible reasons for this unusually large temperature shift are are discussed. [S1063-651X(99)06405- 3].