D. Schlauf et al., Temperature difference between bulk and surface transition in freely suspended smectic films, PHYS REV E, 59(5), 1999, pp. 6188-6191
We report an ellipsometric study of freely suspended films of a chiral liqu
id-crystal compounded possessing the phase sequence smectic-C-smectic-A-iso
tropic with a very broad.(67 K) smectic-A phase range. We observe a smectic
-C-smectic-A surface transition which is, situated more than 60 K above the
bulk smectic-C-smectic-A transition temperature. Possible reasons for this
unusually large temperature shift are are discussed. [S1063-651X(99)06405-
3].