First-principles methods are used to calculate the structures and local vib
rational modes of interstitial oxygen pairs in silicon. The staggered Oi-Si
-Oi and skewed O-i-Si-Si-O-t structures are nearly degenerate in energy. Th
e calculated local vibration frequencies and their pure and mixed O-18 -->
O-16 isotopic shifts agree closely with experiments: the highest frequency
is assigned to the skewed and the four lower ones to the staggered structur
e. This result may clear up the controversy of oxygen dimers in silicon. an
d also suggests a mechanism for fast oxygen diffusion.