A RESOLUTION OF MONODENTATE P-ASTERISK CHIRAL PHOSPHINE

Authors
DUNINA VV GOLOVAN EB
Citation
Vv. Dunina et Eb. Golovan, A RESOLUTION OF MONODENTATE P-ASTERISK CHIRAL PHOSPHINE, Tetrahedron : asymmetry, 6(11), 1995, pp. 2747-2754
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
11
Year of publication
1995
Pages
2747 - 2754
Database
ISI
SICI code
0957-4166(1995)6:11<2747:AROMPC>2.0.ZU;2-8
Abstract
The monodentate phosphine PMeBu(t)Ph is obtained in enantiopure form b y using a new N-chiral ortho-palladated resolving agent; some advanta ges of the latter over its N-achiral analogue are shown. The condition s of resolved phosphine displacement from individual diastereomers of palladium(II) complexes are elaborated which allow the starting resolv ing agent to be recovered.