High-purity precipitated calcium carbonate has been produced in the la
boratory by carbonation of a solution of calcium nitrate and monoethan
olamine. The process was traced by measurements of the change in Ca co
ncentration and in electrical conductivity of the solution. The kappa-
t and c(Ca)-t curves were analyzed to determine the effect of temperat
ure and concentration of carbon(IV) oxide on the process of carbonatio
n. The samples obtained were mainly of aragonite and vaterite crystal
modifications with traces of calcite. The relationship between the min
eralogical composition and particle size (morphology) and operating co
nditions was examined as well.