Syntheses and crystal structures of cdta (trans-cyclohexane-1,2-diamine-N,N,N ',N '-tetra-acetate)-based copper(II) dimers and polymers

Authors
Wang, QM Wu, XT Lin, P Zhang, WJ Sheng, TL Yu, H Chen, L Li, JM
Citation
Qm. Wang et al., Syntheses and crystal structures of cdta (trans-cyclohexane-1,2-diamine-N,N,N ',N '-tetra-acetate)-based copper(II) dimers and polymers, POLYHEDRON, 18(10), 1999, pp. 1411-1417
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
18
Issue
10
Year of publication
1999
Pages
1411 - 1417
Database
ISI
SICI code
0277-5387(1999)18:10<1411:SACSOC>2.0.ZU;2-C
Abstract
Four cdta (trans-cyclohexane-1,2-diamine-N,N,N',N'-tetra-acetate)-based cop per(II) compounds, [(H(2)cdta)Cu(4,4'-bpy)Cu(H(2)cdta)].4,4'-bpy . 2H(2)O ( 1), [(H(2)cdta)Cu(pyz)-Cu(H(2)cdta)]. 14H(2)O (2), [Cu(cdta)Cu(H2O)(3)(4,4' -bpy)](n). 8nH(2)O (3) and [{Cu(cdta)(H2O)(2)}(2)(pyz)](n). 4nH(2)O (4), we re obtained from a Cu2+-diimine-cdta system (4,4'-bpy=4,4'-bipyridine and p yz=pyrazine). The X-ray crystallography analysis shows that 1 and 2 are dii mine-bridged dimers, 3 has an infinite zigzag configuration and 4 contains a 'step ladder'-like structure. (C) 1999 Elsevier Science Ltd. All rights r eserved.